TERPINYL FORMATE

Base Information

  • Chemical Name: TERPINYL FORMATE
  • CAS No.: 2153-26-6

Export Top Purity TERPINYL FORMATE 2153-26-6 In Stock

  • Molecular Formula: C11H18O2
  • Molecular Weight: 182.263
  • Vapor Pressure: 0.0469mmHg at 25°C 
  • Refractive Index: n20/D 1.471(lit.) 
  • Boiling Point: 236.6°Cat760mmHg 
  • Flash Point: 94.7°C 
  • PSA: 26.30000 
  • Density: 0.971g/cm3 
  • LogP: 3.32030 

TERPINYL FORMATE(Cas 2153-26-6) Usage

Preparation

By cold formylation of terpineol, using formic-acetic anhydride (Arctander, 1969). Uses: In public use before the 1920s. Use in fragrances in the USA amounts to approximately 10001b/yr.

Synthesis

May be produced from d-α-terpineol and formic acetic anhydride; the racemic α-terpineol is also obtained by an analogous synthesis.

InChI:InChI=1/C11H18O2/c1-9-4-6-10(7-5-9)11(2,3)13-8-12/h4,8,10H,5-7H2,1-3H3/t10-/m1/s1

2153-26-6 Relevant articles

Discovery of a novel series of α-terpineol derivatives as promising anti-asthmatic agents: Their design, synthesis, and biological evaluation

Zhu, Wanping,Liu, Xia,Wang, Yuji,Tong, Yeling,Hu, Yongzhou

, p. 419 - 425 (2017/12/07)

A series of novel α-terpineol derivative...

Α- [...] enol derivative and its preparation method and application

-

Paragraph 0033; 0034, (2017/05/03)

The invention discloses alpha-terpineol ...

ANTIMICROBIAL COMPOSITION COMPRISING THYMOL AND A TERPINYL DERIVATIVE

-

Page/Page column 29, (2013/03/26)

The present invention relates to an anti...

P-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions

Khazaei, Ardeshir,Rostami, Amin,Mantashlo, Fatemeh

experimental part, p. 1430 - 1434 (2011/10/08)

The catalytic application of p-toluenesu...

2153-26-6 Process route

carboxy chlorine
463-73-0

carboxy chlorine

terpineol
98-55-5,2438-12-2

terpineol

2-(4-methylcyclohex-3-enyl)propan-2-yl formate
2153-26-6

2-(4-methylcyclohex-3-enyl)propan-2-yl formate

Conditions
Conditions Yield
With sodium hydride; In tetrahydrofuran; mineral oil; at 20 ℃; Inert atmosphere;
formic anhydride
1558-67-4

formic anhydride

terpineol
98-55-5,2438-12-2

terpineol

2-(4-methylcyclohex-3-enyl)propan-2-yl formate
2153-26-6

2-(4-methylcyclohex-3-enyl)propan-2-yl formate

Conditions
Conditions Yield
With p-toluenesulfonyl chloride; at 20 ℃; for 1.5h;
15.5%
With p-toluenesulfonyl chloride; at 20 ℃; for 8h;
3.0032 g

2153-26-6 Upstream products

  • 64-18-6
    64-18-6

    formic acid

  • 39864-10-3
    39864-10-3

    α-terpinyl chloride

  • 2258-42-6
    2258-42-6

    formyl acetic anhydride

  • 138-86-3
    138-86-3

    limonene.

2153-26-6 Downstream products

  • 38235-58-4
    38235-58-4

    trans-sobrerol

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