1-METHYL-1,4-CYCLOHEXADIENE

Base Information

  • Chemical Name:1-METHYL-1,4-CYCLOHEXADIENE
  • CAS No.:4313-57-9

Chinese Manufacturer Supply 1-METHYL-1,4-CYCLOHEXADIENE 4313-57-9 On Stock with Competitive Price

  • Molecular Formula:C7H10
  • Molecular Weight:94.1564
  • Vapor Pressure:26.5mmHg at 25°C 
  • Melting Point:<-70℃ 
  • Refractive Index:n20/D 1.471(lit.) 
  • Boiling Point:111.6°Cat760mmHg 
  • Flash Point:2°C 
  • PSA:0.00000 
  • Density:0.848g/cm3 
  • LogP:2.28270 

1-METHYL-1,4-CYCLOHEXADIENE(Cas 4313-57-9) Usage

General Description

1-Methyl-1,4-cyclohexadiene is a chemical compound with the molecular formula C7H10. It is a colorless liquid with a pungent odor and is classified as a flammable liquid. 1-Methyl-1,4-cyclohexadiene is commonly used as a solvent in various industrial processes and as a building block in organic synthesis. It is also used as an intermediate in the production of pharmaceuticals and agrochemicals. The compound is considered to be potentially hazardous as it is a respiratory irritant and can cause skin irritation upon contact. Additionally, it is incompatible with oxidizing agents and strong acids. Therefore, it is important to handle and store 1-methyl-1,4-cyclohexadiene with caution to prevent accidents and exposure.

InChI:InChI=1/C7H10/c1-7-5-3-2-4-6-7/h2-3,6H,4-5H2,1H3

4313-57-9 Relevant articles

Rhodium(I)-Catalyzed Enantioselective C(sp3)—H Functionalization via Carbene-Induced Asymmetric Intermolecular C—H Insertion?

Liu, Bo,Xu, Ming-Hua

supporting information, p. 1911 - 1915 (2021/05/31)

Transition-metal-catalyzed C—H insertion...

Organocatalyzed Birch Reduction Driven by Visible Light

Cole, Justin P.,Chen, Dian-Feng,Kudisch, Max,Pearson, Ryan M.,Lim, Chern-Hooi,Miyake, Garret M.

supporting information, p. 13573 - 13581 (2020/09/03)

The Birch reduction is a powerful synthe...

Substituent effects on the dehydration of arene hydrates in aqueous solution

O'Mahony, Michelle J.,More O'Ferrall, Rory A.,Boyd, Derek R.,Lam, Casey M.,O'Donoghue, Annmarie C.

supporting information, p. 989 - 996 (2014/01/06)

Rate constants have been determined by U...

Reductions of benzene derivatives whose benzylic positions bear oxygen atoms under mild conditions

Menzek, Abdullah,Karakaya, Melek Goekmen,Kaya, Afsin Ahmet

experimental part, p. 2299 - 2307 (2009/03/12)

Reductions of compounds whose benzylic p...

4313-57-9 Process route

benzaldehyde
100-52-7

benzaldehyde

2,5-dihydrotoluene
4313-57-9

2,5-dihydrotoluene

toluene
108-88-3,15644-74-3,16713-13-6

toluene

benzyl alcohol
100-51-6,185532-71-2

benzyl alcohol

Conditions
Conditions Yield
With ammonia; lithium; tert-butyl alcohol; In tetrahydrofuran; at 20 ℃; Cooling with ice;
10.9 %Spectr.
6.7 %Spectr.
8.4 %Spectr.
toluene
108-88-3,15644-74-3,16713-13-6

toluene

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

2,5-dihydrotoluene
4313-57-9

2,5-dihydrotoluene

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

Conditions
Conditions Yield
With lithium; ethylenediamine; isopropyl alcohol; at 85 - 95 ℃; for 0.333333h;
67%

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4313-57-9 Downstream products

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