SODIUM TRIMETHYLSILANOLATE
Base Information
- Chemical Name: SODIUM TRIMETHYLSILANOLATE
- CAS No.: 18027-10-6
Buy Good Quality SODIUM TRIMETHYLSILANOLATE 18027-10-6 with a minimum purity of 99%
- Molecular Formula: C3H9NaOSi
- Molecular Weight: 112.179
- Melting Point: 230 °C (dec.)(lit.)
- Boiling Point: 75 °C at 760 mmHg
- Flash Point: -2 °F
- PSA： 23.06000
- Density: 1.283 g/mL at 25 °C
- LogP: 1.25180
SODIUM TRIMETHYLSILANOLATE(Cas 18027-10-6) Usage
|
Purification Methods |
It is very soluble in Et2O and *C6H6 but moderately soluble in pet ether. It is purified by sublimation at 130-150o in a high vacuum. [Hyde et al. J Am Chem Soc 75 5615 1953, Tatlock & Rochow J Org Chem 17 1555 1952, Beilstein 4 III 1856.] |
InChI:InChI=1/C3H10OSi.Na/c1-5(2,3)4;/h4H,1-3H3;/q;+1
18027-10-6 Relevant articles
HETEROBICYCLIC SPHINGOSINE 1-PHOSPHATE ANALOGS
-
Page/Page column 23, (2010/05/14)
Compounds that have agonist activity at ...
Scope and limitations of sodium and potassium trimethylsilanolate as reagents for conversion of esters to carboxylic acids
Lovric, Marija,Cepanec, Ivica,Litvic, Mladen,Bartolincic, Anamarija,Vinkovic, Vladimir
, p. 109 - 115 (2008/02/04)
Sodium or potassium trimethylsilanolate ...
Monosodiumoxyorganoalkoxysilanes: Synthesis and properties
Rebrov,Muzafarov
, p. 514 - 541 (2007/10/03)
The reaction of organoalkoxysilanes with...
18027-10-6 Process route
-
-
107-46-0
Hexamethyldisiloxane
-
-
18027-10-6
sodium trimethylsilanolate
| Conditions | Yield |
|---|---|
|
With
NaNH2;
In
ammonia;
NH3 (liquid);
|
80%
|
|
With
sodium amide;
In
ammonia;
|
80%
|
|
With
sodium hydroxide;
In
1,2-dimethoxyethane;
for 72h;
Heating;
|
|
|
With
sodium hydroxide;
In
sodium hydroxide;
heating of (CH3)3SiOSi(CH3)3 and aq. NaOH above 100°C in a closed tube;;
|
0%
|
|
With
sodium oxide;
In
pyridine; methanol;
|
|
|
With
sodium amide;
In
ammonia;
|
|
|
With
sodium hydroxide;
In
methanol;
|
|
|
With
sodium hydroxide;
In
1,2-dimethoxyethane;
for 20h;
Inert atmosphere;
Reflux;
|
|
|
With
NaNH2;
In
ammonia;
NH3 (liquid);
|
|
|
With
Na2O;
In
pyridine; methanol;
|
|
|
With
NaOH;
In
methanol;
|
|
|
With
NaOH;
In
sodium hydroxide;
aq. NaOH; heating of (CH3)3SiOSi(CH3)3 and aq. NaOH above 100°C in a closed tube;;
|
0%
|
|
With
Na2O;
In
pyridine; methanol;
heating of (CH3)3SiOSi(CH3)3 and Na2O in pyridine and small amt. of methanol;;
|
|
|
With
methanol; sodium hydroxide;
|
|
|
With
sodium oxide;
In
pyridine; methanol;
heating of (CH3)3SiOSi(CH3)3 and Na2O in pyridine and small amt. of methanol;;
|
-
-
18027-10-6
sodium trimethylsilanolate
| Conditions | Yield |
|---|---|
|
Herstellung;
|
18027-10-6 Upstream products
-
107-46-0
Hexamethyldisiloxane
-
1825-61-2
Trimethylmethoxysilane
-
1825-62-3
ethyl trimethylsilyl ether
-
1066-40-6
Trimethylsilanol
18027-10-6 Downstream products
-
66128-13-0
trimethylsilyldiphenylphosphine oxide
-
2943-62-6
1-chloro-1,1,3,3,3-pentamethyldisiloxane
-
1873-88-7
1,1,1,3,5,5,5-heptamethyltrisiloxan
-
2096-83-5
tetraphenyldiphosphine oxide
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